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The Nutritional Value of Algae Applications Of Seaweed Information on the Carrageenan
The Nutritional Value Of Algae
Seaweed has very rich mineral elements which comprise 36% of its dry mass. These include sodium, calcium, magnesium, potassium, chlorine, sulphur and phosphorus, whereas the trace elements are iodine, iron, zinc, copper, selenium, molybdenum, fluorine, manganese, boron, nickel and cobalt. Among the many mineral elements contained in seaweed, iodine deserves a special mention, as the iodine content of seaweed is particularly high, allowing seaweed to serve as a source of iodine, helping to fulfil one's Daily Recommended Intake of iodine. Among the various types of seaweed, brown algae contain the highest levels of iodine content. In most cases, red and green algae contain lower iodine content levels than brown algae. However, it is still much higher than any land-based plant. A lack of iodine in the human body will lead to the abnormal functioning of the thyroid gland, as it uses iodine to synthesise the thyroid hormone.

Aside from iodine, seaweed is the richest plant source of calcium. Calcium is required for the formation of human skeletal and dental components as well as to maintain the normal function of the cell membrane. It is also important to maintain a regular intake of calcium, as the human body loses calcium everyday through various functions. The replenishment of the lost calcium is especially important during a child's growing stage. Certain types of seaweed contain large amounts of magnesium, which helps to relieve stress and prevent heart diseases caused by tension.

Seaweed also contains copper, which is associated

The Nutritional Of Algae

with the absorption of iron into the body. However, an overdose of copper, zinc and manganese in human body can cause toxicity and lead to liver damage. Research indicates that manganese, blood glucose levels and the occurrence of epilepsy are interrelated. The facts above state that a balance of mineral levels and the occurrence of epilepsy are interrelated. The facts above state that a
balance of mineral elements in our body is an important factor in maintaining a healthy body. Therefore, we must maintain an appropriate level of major and trace elements in our bodies. Daily consumption of seaweed may replenish a variety of inorganic elements in our body.

The protein content in seaweed is slightly different in the varying types of algae. Brown algae have 5-11% of their dry mass as protein while red algae have 30-40% of their dry mass as protein. This content is almost equivalent to the protein content in legumes. Besides, the protein content of green algae is as high as 20% of their dry mass. Spirulina and micro-algae are well-known to contain high protein contents up to 70% of their dry mass.

The vitamins that are contained within seaweed are carotenoids, vitamin B1, B2, B12 and vitamin C. The fat content of algae is low, ranging from 1-5% of their dry mass, but their essential fatty acids levels are still higher than terrestrial plants. Green algae are rich in oleic acid and a-linoleic acid. Seaweed has high fibre content, about 32-50% of its dry mass. Research shows that seaweed fibre has properties including antioxidant, anti-mutation, anti-coagulation, anti-tumor agents as well as agents that enhance human lipid metabolism. The soluble fibre in green and red algae is about 51-56% of the total fibre content whereas the amount in brown algae is about 67-87% of the total fibre content. Generally, soluble fibres have cholesterol-lowering and hypoglycemic effects.
Applications Of Seaweed
As technology continues to develop, the use of seaweed has also become increasingly widespread, expanding beyond the boundaries of food and nutrition. Aside from food processing and application industries, it can also be processed into bio-fuel to fulfil the global demand for energy. The uses of seaweed have multiplied rapidly and this has become an economic growth factor in recent years.

Carrageenan is principally used as an ingredient in the processing of food products as a stabiliser, binder and emulsifier. More specifically, the various end uses of carrageenan can be classified under two sections: food and non-food, wherein the former accounts for nearly 70% of the world demand for the product.

The many uses of seaweed include the following:

Tyre
Cosmetic and skin care products
Bio-fuel
Medication
Pharmaceutical industry
Colour binding
Food binding
Explosive material
Anti-earthquake material
Plastic bags and wrappings
Toothpaste and soap
Condoms
Food, e.g. sausages, corn beef, ham, meatballs, ice cream, puddings, etc
Frozen foods
Paper
Information on the Carrageenan
Carrageenan is a collective term for polysaccharides prepared by alkaline extraction (and modification) from red seaweed (Rhodophycae) , mostly of genus Chondrus, Eucheuma, Gigartina and Iridaea. Different seaweeds produce different carrageenans.

Carrageenans are linear polymers of about 25,000 galactose derivatives with regular but imprecise structures, dependent on the source and extraction conditions.
Structural Unit
Carrageenan consists of alternating 3-linked-β-D-galactopyranose and 4-linked-α-D-galactopyranose units.
Functionality
Carrageenans are used mainly for thickening, suspending and gelling. κ- and ι-carrageenans form thermoreversible gels on cooling in the presence of appropriate counter ions.  κ-Carrageenan forms a firm clear, if brittle, gel with poor freeze-thaw stability; the coil-double helix transition being followed by a K+-induced aggregation of the helices . κ-Carrageenan gels may be softened (and is generally regarded to be synergistically strengtheneda) with locust bean gum. ι-Carrageenan has less specific ionic binding but increased ionic strength allows helices to form junction zones in soft elastic gels with good freeze-thaw stability. λ-Carrageenan is non gelling as the lack of the 1C4 3,6-anhydro-link allows the galactose residues to revert to their 4C1 conformation which does not allow the initial double helix formation required for gelling. Additionally, the high density of charged sulfate groups encourages an extensive conformation. λ-Carrageenan has been found to act as a cryoprotectant animproves the freeze-thaw behavior of locust bean gum.

κ-Carrageenan stabilizes milk κ-casein products due to its charge interaction with the casein micelles (~200 nm diameter); their incorporation into the network preventing whey separation. Such complexes are soluble when both have same charge and are held together by counter ions or oppositely charged patches. Carrageenan is also used as a binder in cooked meats, to firm sausages and as a thickener in toothpaste and puddings.
Molecular structure
Carrageenans are linear polymers of about 25,000 galactose derivatives with regular but imprecise structures, dependent on the source and extraction conditions. Idealized structures are given below and κ-carrageenan, for example, has been found to contain a small proportion of the dimer associated with ι-carrageenan.
κ-carrageenan (kappa-carrageenan)

-(13)-β-D-galactopyranose-4-sulfate-(14)-3,6-anhydro-α-Dgalactopyranose-(13)-




κ-carrageenan is produced by alkaline elimination from μ-carrageenan] isolated mostly from the tropical seaweed Kappaphycus alvarezii (also known as Eucheuma cottonii). The experimental charge/dimer is 1.03 rather than 1.0 with 0.82 molecules of anhydrogalactose rather than one.
ι-carrageenan (iota-carrageenan)

-(13)-β-D-galactopyranose-4-sulfate-(14)-3,6-anhydro-α-Dgalactopyranose-2-sulfate-(13)-



ι-carrageenan is produced by alkaline elimination from ν-carrageenan isolated mostly from the Philippines seaweed Eucheuma denticulatum (also called Spinosum). The experimental charge/dimer is 1.49 rather than 2.0 with 0.59 molecules of anhydrogalactose rather than one. The three-dimensional structure of the ι-carrageenan double helix has been determined as forming a half-staggered, parallel, threefold, right-handed double helix, stabilized by interchain O2-H···O-5 and O6-H···O-2 hydrogen bonds between the β-D-galactopyranose-4-sulfate units. The structure of some calcium iota-carrageenans have been determined.
λ-carrageenan (lambda-carrageenan)

-(13)-β-D-galactopyranose-2-sulfate-(14)-α-D-galactopyranose-2,6-disulfate-(13)




λ-carrageenan (isolated mainly from Gigartina pistillata or Chondrus crispus) is converted into θ-carrageenan (theta-carrageenan) by alkaline elimination, but at a much slower rate than causes the production of ι-carrageenan and κ-carrageenan. The experimental charge/dimer is 2.09 rather than 3.0 with 0.16 molecules of anhydrogalactose rather than zero.
Related Link:
TOYOTA wants to build car from seaweed
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http://www.drive.com.au/Editorial/ArticleDetail.aspx?ArticleID=61084
http://www.caradvice.com.au/22825/toyota-engineer-dreams-of-cars-made-from-seaweed/
http://www.gizmag.com/toyota-1x-seaweed-hybrid/11096/
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Electricity from seaweed
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China National Petroleum corporation
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Korea & Jakarta invest in seaweed as biofuel, tackle global warming
http://www.thejakartapost.com/news/2009/03/11/indonesia-south-korea-develop-seaweed-power.html
http://www.thejakartapost.com/news/2009/03/10/ri-s-korea-develop-biofuel-seaweed.html
Nordic Energy Solutions - Biofuel from seaweed
http://www.nordicenergysolutions.org/inspirational/biofuel-from-seaweed
Biofuel harvested from seaweed
http://www.thebioenergysite.com/news/5021/biofuel-harvested-from-seaweed
Develop seaweed into fuel
http://www.northernireland.gov.uk/news/news-deti/news-deti-june-2010/news-deti-170609-seaweed-could-hold.htm
Denmark turns common seaweed to biofuel
http://www.ambathen.um.dk/en/menu/AboutUs/Climate+change/DENMARKLOOKSTOTURNACOMMONSEAWEEDINTOBIOFUEL.htm?wbc_purpose=bas